Are you brand new to lifting? If so I would recommend you try out a 5x5 program like Starting Strength, Stronglifts, or Madcow (my favorite, but it really doesn't matter which).
Starting Strength (the book) will also help you learn a ton about technique and how to do the lifts, etc.
If you're not so new, and know the lifts, etc. you could try Madcow (intermediate or advanced), WS4SB, or Jim Wendler's 5/3/1. All simple and easy to learn programs.