Couple of things:
Get seriously strong on your arm exercises... Alt. Curl the 80's-100's (i.e. 35-45 Kilos per arm or so) for a good number of reps... Do EZ Extensions with 185+ (85+ Kg) for reps (bar coming down behind head, you're lying on the flat bench, shoulders stay on the bench, upper arms stop at an incline, not perpendicular to the floor)... Some tricep pressing movement (CG Bench, pin press, IH or SWRGB or whatever), lots of weight for reps... That kind of stuff, but of course you don't actually have to get all the way there, it depends on just how big you want your arms to be... And exercise selection is an individual thing, I'm just giving examples there.
Gain bodyweight (and get strong all over, sort of goes without saying... and eat enough to gain weight... Shoot for about 1.5-2 grams of protein per lb of bodyweight... 1.5 is a good starting point, once you get over 220 or so you might really want to consider going towards 1.8 or so, but ultimately you also have to eat enough fat and carbs, ratios depend on what works best for you, to grow and gain strength at a good pace...
Usually, the stronger you get on arm work (any exercise letting your arms do most of the work, really) compared to your bodyweight, the bigger your arms should end up being at that weight... Thing is, at 180 lbs at your height, you definitely will have to gain weight in order to get your arms up to a nice level of size... 6'3 180 lbs guys just don't have big arms usually.
If you need me to be more specific, just ask... And of course there is more than one way to skin the cat, but ultimately it all boils down to progression in body and exercise -weight to some degree.