Beginner - 531 PPS (push/pull/squat)
Day 1 Squat 531 1x5x55% 1x5x65% 3x5x75%
DB Rows 3 sets high reps
Close grip bench press 3x10
Day 2 Bench Press 531
Chin ups or Barbell Row 3 sets
Day 3 Deadlift 531
DB Bench Press 3 sets
%'s are based on actual 1RM, not the 90% thing. No point in making the math that much harder. Takes away the extra step.
Then go to the 3 rep days and then the 531 days. This will give the beginner enough volume to start with. Basically like a 5x5 with the first two worksets at a lower weight. I would take a month or so and figure out an estimated or actual 1RM before beginning this program.
I would also teach them to listen to their body for rest/recovery. I'm not a fan or advocate of setting aside certain days. Hit it when your body is ready to get the most out of it.
I personally use this program as Wendler designed it (3x5 3x3 531), but for beginners, the extra volume at the higher percentages will help.
I do not follow set days. Generally w/ this program, I can go 3 days on and 1 day off. It allows me to train more often (which I like) w/o burning out. If I need an extra day, I take it. It also hits my entire body.
The only other thing I will do is neck/rhomboids/trap stuff for a couple sets per session. But that's me.